Once you pass 3Tb of storage to include the full storage amount of all drives, you can have a problem.
!st, make darn sure the mtrbd. bios is fully updated to the latest release. Then the HDs have to be GPT'ed in order to fully use the storage available or acknowledge them. If the mtrbd. itself is older even though new it may not the " I/F guts" akin to bios to accept larger than 3Tbs or similar. You have a mtrbd. clearly state it can handle 3tb and beyond to include any RAID setup. That too maybe at fault because RAID connections may limit what it can handle if only to assured it can handle it period. You may to return the mtrbd. is not up-t-date on the newest demands out there and thus pay for a premium for a more capable one.
Last, try it only with one(1) 4Tb drive installed and see how it handles that. BUT, before doing that, be sure you have a fully updated bios and all MS updates have been gotten. Also, the HD maker may more readily answer your query if you check the Q&A or find the FAQ or review the support website of same. You know 2-$tb is NOT a typical user setup and you may have jumped the gun in making it all work. At least if it doesn't than the shop better be prepared if brought there to provide a more capable solution beyond what you already have in h/w at least. yeah, it will cost more, sorry.
tada -----Willy 