I found a website that lists user submitted codes. Hopefully it can help you out, depending on the model. Sky codes may not work for newer televisions (depending on the version and revision you have), but since you've worked with it more than I have, maybe you can make sense of the revisions and codes.
SKY+ Rev 6
Paul C, Renko
LE40A656A1FX /SERIES 6
SKY+ Rev 8
And here's the link where I found it:
I have samsung 40 inch Lcd tv
I am trying to pair it up with my sky remote.
cant find keys to pair it up and control tv from sky remote.
otherwise bangon tv once you have turned down brightness from standard settings. It was blinding when I first turned it on.