and possibly the best, free, software is CDBurnerXP but whether that is suitable and how you do this depends on a number of factors, so can you tell us more?

1] What is the OS, (Operating System), on this computer working?

2] What make and model computer and what OS?

3] Does this computer have a CD Burner drive, eg a drive that is CDR/RW. If so, does that drive work?

4] Does this computer have USB ports? If so, a USB stick might be easier and quicker than burning to CD.

Photos are just files with a file extension of .BMP or .JPG, or .TIFF, so you could search your OS for all .bmp, .jpg, .tiff files, and then copy them to a USB stick.

Mark