Thanks for your message! But just so you know, I support US products and customers. And from what I can tell, this model is for the UK. (Correct me if I'm wrong.) So if you want the most accurate information, here's the Samsung UK portal for support on that product: http://www.samsung.com/uk/support/model/UE46ES6100WXTK
From everything I have found, this camera will not work with this TV. But to be sure you should contact the support for your country.
Hope this helps you!
Does VG-STC3000 Webcam fit to my UE46ES6100 Smart TV?