Just bought this TV yesterday, I found the settings for the Samsung un32eh4000 TV. Here is the link for these settings.
Perform them in Standard Mode.
I tweaked some of the settings a little for my liking. There are also some setting not mentioned in this chart. I just kept those at the default settings.
This will give you a good start.
Just purchased this TV over the weekend and curious what the best picture settings would be for it. Haven't been able to find any suggestions. Thanks